Heat the oven to 180 C. Wash the peppers and pat them dry. Cut them into quarters. Remove the seeds and pink membrane. Place on a baking tray, skin side up. Drizzle with 3 tablespoons of olive oil. Sprinkle with the oregano and salt and pepper to taste. Bake for 20 minutes. Turn the peppers over and drizzle with the vinegar. Continue baking for a further 20 minutes or until slightly brown at the edges. Remove from the oven and allow to cool. Place in a plastic storage container with a lid. Cover with remaining olive oil. Store in the fridge until needed.
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